首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   40892篇
  免费   3456篇
  国内免费   8420篇
安全科学   4946篇
废物处理   897篇
环保管理   6543篇
综合类   25280篇
基础理论   4562篇
环境理论   28篇
污染及防治   3219篇
评价与监测   2511篇
社会与环境   2946篇
灾害及防治   1836篇
  2024年   110篇
  2023年   702篇
  2022年   1182篇
  2021年   1515篇
  2020年   1499篇
  2019年   1276篇
  2018年   1150篇
  2017年   1500篇
  2016年   1735篇
  2015年   1909篇
  2014年   2030篇
  2013年   2756篇
  2012年   3082篇
  2011年   3374篇
  2010年   2380篇
  2009年   2393篇
  2008年   1890篇
  2007年   2802篇
  2006年   2825篇
  2005年   2261篇
  2004年   1915篇
  2003年   1984篇
  2002年   1667篇
  2001年   1455篇
  2000年   1325篇
  1999年   1180篇
  1998年   852篇
  1997年   715篇
  1996年   572篇
  1995年   523篇
  1994年   481篇
  1993年   410篇
  1992年   301篇
  1991年   210篇
  1990年   148篇
  1989年   81篇
  1988年   76篇
  1987年   60篇
  1986年   41篇
  1985年   45篇
  1984年   35篇
  1983年   35篇
  1982年   38篇
  1981年   36篇
  1980年   35篇
  1979年   34篇
  1978年   22篇
  1977年   20篇
  1973年   23篇
  1971年   25篇
排序方式: 共有10000条查询结果,搜索用时 187 毫秒
61.
The most widely used method for fetocide in late termination of pregnancy for fetal abnormalities (TOPFA) consists of injecting of potassium chloride (KCl) into the fetal heart and is likely to be painful after 22 weeks of gestation. We studied ten consecutive women undergoing TOPFA between 22 and 38 weeks. This technique for fetocide consisted of a single umbilical vein puncture under ultrasound guidance with injections of sufentanil 5 µg followed by KCl 2 g. No electrocardiographic modifications could be observed and maternal plasma potassium levels did not show any significant variation throughout the procedure. Fetal umbilical phlebotomy for fetal analgesia followed by fetocide therefore appears to be a safe procedure for the mother and allows the fetus to die without pain when late termination of pregnancy (TOP) is indicated. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
62.
BACKGROUND, AIMS AND SCOPE: Chromium enters into the aquatic environment as a result of effluent discharge from steel works, electroplating, leather tanning industries and chemical industries. As the Cr(VI) is very harmful to living organisms, it should be quickly removed from the environment when it happens to be contaminated. Therefore, the aim of this laboratory research was to develop a rapid, simple and adaptable solvent extraction system to quantitatively remove Cr(VI) from polluted waters. METHODS: Aqueous salt-solutions containing Cr(VI) as CrO4(2-) at ppm level (4-6 ppm) were prepared. Equal volumes (5 ml) of aqueous and organic (2-PrOH) phases were mixed in a 10 ml centrifuge tube for 15 min, centrifuged and separated. Concentrations of Cr(VI), in both the aqueous and organic phases, were determined by atomic absorption spectrometry. The effects of salt and acid concentrations, and phase-contact time on the extraction of Cr(VI) were investigated. In addition, the extraction of Cr(VI) was assessed in the presence of tetramethylammonium chloride (TMAC) in 2-PrOH phase. Effects of some other metals, (Cd(II), Co(II), Cu(II), Ni(II) and Zn(II)), on the extraction of Cr(VI) were also investigated. RESULTS AND DISCUSSION: The Cr(VI) at ppm level was extracted quantitatively by salting-out the homogeneous system of water and 2-propanol(2-PrOH) using chloride salts, namely CaCl2 or NaCl, under acidic chloride media. The extracted chemical species of Cr(VI) was confirmed to be the CrO3Cl-. The ion-pair complex extracted into the organic phase was rationalized as the solvated ion-pair complex of [2-PrOH2+, CrO3Cl-]. The complex was no longer stable. It implied the reaction between extracted species. Studies revealed that salts and acid directly participated in the formation of the above complex. Use of extracting agents (TMAC) didn't show any significant effect on the extraction of Cr(VI) under high salting-out conditions. There is no significant interference effect on the extraction of Cr(VI) by the presence of other metals. The Cr(VI) in the organic phase was back-extracted using an aqueous ammonia solution (1.6 mol dm(-3)) containing 3 mol dm(-3) NaCl. The extraction mechanism of Cr(VI) is also discussed. CONCLUSIONS: Salting-out of homogeneous mixed solvent of 2-propanol can be employed to extract Cr(VI) quantitatively, as an ion-pair of [2-PrOH2+ * CrO3Cl-] solvated by 2-PrOH molecules. Then, the complex becomes 'solvent-like' and is readily separated into the organic phase. The increase of Cl- ion concentration in the aqueous phase favors the extraction. The 2-PrOH, salts and acid play important roles in the extraction process. There is no need to use an extracting agent at a high salting-out condition. RECOMMENDATIONS AND PERSPECTIVES: Chromium(VI) must be quickly removed before it enters into the natural cycle. As the 2-PrOH is water-miscible in any proportion, ion-pairing between 2-PrOH2+ and CrO3Cl- becomes very fast. As a result, Cr(VI) can easily be extracted. Therefore, the method is recommended as a simple, rapid and adaptable method to quickly separate Cr(VI) from aqueous samples.  相似文献   
63.
The methodology of materials accounting is presented and applied to developing nutrient balance (nitrogen and phosphorus) in a river basin. The method is based on the balance principle: inputs and outputs of each nitrogen and phosphorus related sub-systems were balanced. The application of the methodology strategies was illustrated by means of a case study of the Krka river, Slovenia. Different pathways of emission to surface waters were taken into account: WWTP discharges, direct discharges, erosion/runoff and baseflow. Total annual emission into the river Krka was estimated to be 362 tonnes N/year and 73.3 tonnes P/year. The main sources of nitrogen are diffuse sources, emitted via baseflow (52%). Other important sources are effluents from WWTP, which account for 36% of total emissions. Other sources like erosion and direct discharges to surface water (animal manure, industry, households) are of lower magnitude. Erosion is main source of phosphorus emission (55% of total emission), WWTP effluents account for 37% of total emission, while other sources are less important. Besides reduction of point sources by means of wastewater collection and implementation of nutrient removal technology, managing agricultural nitrogen and phosphorus to protect water quality should become a major challenge in the Krka river basin.  相似文献   
64.
防灾预案研究   总被引:1,自引:0,他引:1  
陆立德  徐旭初 《灾害学》1992,7(2):17-20
本文提出了防御灾害预案的五要素和逻辑结构,进而讨论了防灾预案的优化准则、制定程序等问题。  相似文献   
65.
针对某乡镇企业十分发达地区的跨行政(市县)区域水污染死鱼事故的剖析,本文提出了处理解决跨行政区域水污染纠纷事故的若干对策建议。  相似文献   
66.
A case of type III congenital cystic adenomatoid malformation of the lung was successfully diagnosed prenatally by fetal lung biopsy. We performed this procedure at 22 weeks of gestation, using a biopsy gun system under ultrasound guidance. The pregnancy was undisturbed by the procedure but as the condition was incompatible with life, an abortion was performed. The diagnosis was confirmed at post-mortem examination. Fetal lung biopsy appears to be a useful method for prenatal diagnosis of fetal lung disorders.  相似文献   
67.
68.
岷江上游崩塌滑坡分布规律研究   总被引:1,自引:0,他引:1  
岷江为长江—级支流,上游长330km,自1986年以来,发生崩塌滑坡200余处,体积约2.1亿m ̄3。作者研究了岷江上游崩塌滑坡的分布规律。采用统计指标法,将岷江上游分为三种不同的崩塌滑坡分布密度区:①UXS.高密度区;②MXS,中密度区;③LXS_3低密度区。  相似文献   
69.
三峡工程与长江中游沿江产业带建设   总被引:3,自引:0,他引:3  
讨论了长江中游沿江产业带发展条件、限制因素和未来发展,指出三峡工程的建设将对长江中游产业的布局和经济发展带来深刻的变化;防洪作用促进中游两岸大型工业项目的兴建,调整现有沿江城镇的布局,使之结构趋于合理化;电力供应经解能源的紧张状态,改善航运条件,发挥长江黄金水道的综合效益。当然,由于坝下河道冲刷,对现有的码头带来一定的影响,由于冬季水位抬升引起两岸低湖田地下水位上升,加剧两岸土壤潜育化和沼泽化。  相似文献   
70.
Ligustrum lucidum Ait. f. tricolor (Rehd.) Rehd. in relation to atmospheric pollutants in Córdoba city, Argentina. The study area receives regional pollutants and was categorized taking into account traffic level, industrial density, type of industry, location of the sample point in relation to the street corner, treeless condition, and topographic level. Dried weight/fresh weight ratio (DW/FW) and specific leaf area (SLA) were calculated, and concentrations of chlorophylls, carotenoids, total sulfur, soluble proteins, malondialdehyde (MDA), and hydroperoxy conjugated dienes (HPCD) were determined in leaf samples. Sulfur content correlates positively with traffic density and SLA correlates negatively with some combinations of the categorical variables; MDA correlates positively with topographic level and total protein concentration correlates negatively with treeless condition. On the basis of our results, traffic, location of trees, type of industry, situation of a tree with respect to others, and topographic level are the environmental variables to bear in mind when selecting analogous sampling points in a passive monitoring program. An approximation to predict tree injury may be obtained by measuring DW/FW ratio, proteins, pigments, HPCD, and MDA as they are responsible for the major variability of data.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号